Question
Give the name of each ligand present in the $\mathrm{Nb}$ complex of the previous question as it will be named in the nomenclature for coordination compounds.
Step 1
This requires reviewing the structure of the complex to determine which molecules or ions are coordinated to the $\mathrm{Nb}$ center. Show more…
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ligands: water monodentate, oxalate bidentate, glycinate bidentate, carbonate bidentate, phenanthroline bidentate, nitrite monodentate, ammonia monodentate, cyanide monodentate, ethylenediamine bidentate. For each of the 9 ligands given , draw out the structure of the homoleptic octahedral cobalt(III) complex. Clearly showing if there is a charge on the overall complex.
Use the Handbook of Cbemistry and Pbysics or a suitable internet site to find rules and examples of nomenclature of coordination compounds. (a) Give the formulas and names of two anionic ligands that are not listed in this chapter. (b) Give the formula and name of a neutral ligand that is not listed in this chapter. (c) Give the formula of a complex that includes each of these ligands.
Name the following coordination compounds (Section 28.3): (a) $\left[\mathrm{NiI}\left(\mathrm{NH}_{3}\right)_{5}\right] \mathrm{NO}_{3} ;$ (b) $\mathrm{K}\left[\mathrm{Co}(\mathrm{ox})_{2}\left(\mathrm{H}_{2} \mathrm{O}\right)_{2}\right] ;$ (c) $\left[\mathrm{Fe}(\mathrm{dien})_{2}\right] \mathrm{SO}_{4} ;$ (d) $\mathrm{Na}\left[\mathrm{AuBr}_{2} \mathrm{Cl}_{2}\right]$.
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