Three acid samples are prepared for titration by $0.01 M$ $\mathrm{NaOH}:$
1. Sample 1 is prepared by dissolving $0.01 \mathrm{~mol}$ of $\mathrm{HCl}$ in $50 \mathrm{~mL}$ of water.
2. Sample 2 is prepared by dissolving $0.01 \mathrm{~mol}$ of $\mathrm{HCl}$ in $60 \mathrm{~mL}$ of water.
3. Sample 3 is prepared by dissolving $0.01 \mathrm{~mol}$ of $\mathrm{HCl}$ in $70 \mathrm{~mL}$ of water.
(a) Without performing a formal calculation, compare the concentrations of the three acid samples (rank them from highest to lowest).
(b) When the titration is performed, which sample, if any, will require the largest volume of the $0.01 M \mathrm{NaOH}$ for neutralization?