00:01
So here we're looking at some hbr addition or some halogenation onto an alkene.
00:09
So if we first start off with what looked like butene with the alkyne there at the first position, if we were to treat it with some hbr, basic mechanism here is the electrons in this sb2 orbital.
00:31
Will pick up this hydrogen and break that bond basically to form two forms of a carbokadion, either at this site or at this site.
00:47
But since we know the two position is a much more stable secondary carbocadion compared to the primary, so then we will get substitution at that site.
01:00
There we are, to now have two bramobutane.
01:05
Okay, the next compound was a cyclopentine, a methylcyclopentine.
01:19
Okay, at that site there, so then the exact same thing is going to happen.
01:23
When we treat it with hbr, we basically formed two intermediates in resonance with each other.
01:32
So resonance with over here.
01:42
So then, there, so then we always pick the cyclet is most substituted.
01:50
So here we have tertiary versus secondary.
01:54
So this will be a lot more selective for the one bromination.
02:04
To make one one methyl bromopentane.
02:09
Okay, so now that we know the mech, we can quickly run through this...