Which of the following compounds can form a buffer solution?
a. $\mathrm{Na}_{2} \mathrm{HPO}_{4}$ and $\mathrm{NaH}_{2} \mathrm{PO}_{4}$
b. $\mathrm{HCl}$ and $\mathrm{NH}_{4} \mathrm{Cl}$
c. $\mathrm{CH}_{3} \mathrm{COOH}$ and $\mathrm{HCOOH}$
d. $\mathrm{Na}_{3} \mathrm{PO}_{4}$ and $\mathrm{NaOH}$