1. (5 pts)
(a) Considering that the Radius Ratio is (y = rsmall /flarge), (1) which one has
the smallest hole size and (2) which one has 6 coordination?
(among cubic holes, octahedral holes and tetrahedral holes)
(1)
(2)
2. (15 pts) (b) The following figure describes perovskite structure. Based
on this figure, answer the following questions.
B
(0,1)
(0,1)
(a)
(b)
(c)
Perovskite structure (ABX3) A & B: cataion, X: anion
(a) What is the hole type of A cation for B cation?
(b) What is the hole type of B cation for X anion?
(c) What is the hole type of X anion for B cation?
3. (10 pts) Explain the following questions!
[Cu2O, CuO, Fe2O3, FeO, V2O5, FeS ]
(a) Select p-type semiconductors among metal oxides appeared!
(b) Select n-type semiconductors among metal oxides appeared!
(c) In case of the O2 partial pressure increase, the conductivity of p-type
metal oxides increased. Explain this phenomenon precisely considering
the oxidation state of metal cation!