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The protease papain from papaya is used in the biotech industry to cleave antibodies into useful fragments. The crystal structure of the papain active site (carbons are in white) is shown below with a covalently bound peptide analogue (carbons in black). When chromogenic esters are used as substrates, papain displays burst phase kinetics.

          The protease papain from papaya is used in the biotech industry to cleave antibodies into useful fragments. The crystal structure of the papain active site (carbons are in white) is shown below with a covalently bound peptide analogue (carbons in black). When chromogenic esters are used as substrates, papain displays burst phase kinetics.
        
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The protease papain from papaya is used in the biotech industry to cleave antibodies into useful fragments. The crystal structure of the papain active site (carbons are in white) is shown below with a covalently bound peptide analogue (carbons in black). When chromogenic esters are used as substrates, papain displays burst phase kinetics.

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Biology for AP Courses
Biology for AP Courses
Julianne Zedalis, John Eggebrecht
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Draw the likely mechanism of peptide bond hydrolysis by papain, including arrows for electron pushing. Label any tetrahedral intermediates. The protease papain from papaya is used in the biotech industry to cleave antibodies into useful fragments. The crystal structure of the papain active site (carbons are in white) is shown below with a covalently bound peptide analogue (carbons in black). When chromogenic esters are used as substrates, papain displays burst phase kinetics. Gln-19 Substrate Cys-25 Asn-175 His-159
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