Problem 3 Identical Particles (10 Marks)
a The Hamiltonian H for two noninteracting particles in an infinite one-dimensional square well of width a is
- (hbar^2/2m)(d^2psi/dx1^2) - (hbar^2/2m)(d^2psi/dx2^2) = Epsi if 0 <= x1, x2 <= a, otherwise psi = 0
If the particles are distinguishable, then the solution can be written as a simple product of the wavefunctions representing each particle. Show that this simple product composite wavefunction formed from the two one-particle states psi_n1(x) = sqrt(2/a) sin(n1 pi x1/a) and psi_n2(x) = sqrt(2/a) sin(n2 pi x1/a) is an eigenfunction of H with energy En1,n2 = (n1^2 + n2^2) pi^2 hbar^2 / 2ma^2.
b Give the eigenfunctions, energies and degeneracies of (i) the ground state and (ii) the first excited state of this system of two distinguishable particles.
c Repeat (b) when the two particles are (i) bosons. (Hint: Remember that for bosons, the wavefunctions are given by (sqrt(2/a))(psi_n1(x) + psi_n2(x))
d What is the ground state wavefunction and energy if the two particles are fermions?
e Show that the average energy per free electron (Etot/Nq) as a fraction of the Fermi energy is given by (3/5)EF.